Adjust oven rack to lowest position. Preheat oven to 350°F. Line #9x13 pan{} with #parchment paper{} or greased-foil. Whisk @Dutch-processed cocoa{1/3%cup}, optional @espresso powder{1.5%tsp}, and boiling @water{10%Tbsp}. Mix until smooth. Add chopped @unsweetened chocolate{2%oz} and whisk until it is melted. Add @eggs{2}, @egg yolks{2}, melted @unsalted butter{4%Tbsp}, and @vanilla{2%tsp}; continue to whisk until smooth. Mix in @sugar{2.5%cup}, @flour{1.75%cup}, and @salt{3/4%tsp}. Fold in @bittersweet chocolate{6%oz} 1/2" pieces. Pour into prepared pan and bake 30 to ~{35%minutes}, rotating pan halfway through. Transfer pan to wire rack and cool for ~{1.5%hours}. Lift parchment paper with brownies in it, and cool on rack for ~{1%hour}.